SAFETY DATA SHEET
Durabak M26 (Military) Safety Data Sheet
OSHA 29 CFR 1910.1200 / GHS Revision 7 - MDI (Aromatic), MIL-PRF-32171B
Section 1. Identification
- Product identifier
- Durabak M26 (Military, smooth)
- Other means of identification
- Durabak M26; military smooth coating
- Note on chemistry
- M26 uses MDI (aromatic isocyanate) chemistry and is
the aromatic mil-spec grade meeting MIL-PRF-32171B revision B. For UV-exposed applications requiring aliphatic/non-yellowing chemistry, see Durabak-18 (IPDI grade).
- Recommended use
- Moisture-cured, single-component polyurethane protective
coating for military and defense applications. Meets MIL-PRF-32171B revision B. Qualified under MIL-PRF-32171B and NAVSEA Std Item 009-32. Suitable as a truck bed liner, deck coating, and protective surface coating. Smooth (non-textured) finish.
- Uses advised against
- Industrial and consumer protective coating only.
Follow label and this SDS. Not for permanent exterior UV exposure (ambers and fades; use MDI-compatible topcoat or Durabak-18 IPDI grade for UV-exposed surfaces).
Supplier (manufacturer/importer): Durabak Bergenfield, NJ 07621, USA
Telephone: 303-690-7190
Web: durabakcompany.com
- Emergency telephone
- 1-800-222-1222 (Poison Help - US national poison control hotline)
Section 2. Hazard(s) Identification
2.1 GHS Classification (OSHA 29 CFR 1910.1200 / GHS Rev 7)
- Flammable Liquids - Category 3 (H226)
- Skin Irritation - Category 2 (H315)
- Skin Sensitization - Category 1 (H317, from MDI - isocyanate)
- Eye Irritation - Category 2 (H319)
- Acute Toxicity (inhalation/dermal) - Category 4 (H312, H332)
- Respiratory Sensitization - Category 1 (H334)
- Specific Target Organ Toxicity, Single Exposure (Respiratory Tract Irritation) - Category 3 (H335)
- Carcinogenicity - Category 2 (H351)
- Specific Target Organ Toxicity, Repeated Exposure (inhalation) - Category 2 (H373)
Signal word: WARNING
Pictograms:
- GHS02 (Flame)
- GHS07 (Exclamation mark)
- GHS08 (Health hazard)
2.2 Hazard Statements
| Code | Statement |
|---|---|
| H226 | Flammable liquid and vapour |
| H312 | Harmful in contact with skin |
| H315 | Causes skin irritation |
| H319 | Causes serious eye irritation |
| H312 + H332 | Harmful in contact with skin or if inhaled |
| H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
| H335 | May cause respiratory irritation |
| H351 | Suspected of causing cancer |
| H373 | May cause damage to organs through prolonged or repeated inhalation exposure |
2.3 Precautionary Statements
| Code | Statement |
|---|---|
| P210 | Keep away from heat, sparks, open flames, hot surfaces. No smoking. |
| P280 | Wear protective gloves, protective clothing, eye protection, face protection. |
| P284 | In case of inadequate ventilation wear respiratory protection. |
| P302 + P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do - continue rinsing. |
| P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
| P501 | Dispose of contents/container to landfill site after solidification. |
2.4 Label Special Provisions
Contains isocyanates. May produce an allergic reaction. Hazard-determining component(s) for labelling: Xylene (mixed isomers).
2.5 Other Hazards
No specific dangers known, if the regulations/notes for storage and handling are considered.
- Note on MDI respiratory sensitization
- MDI (diphenylmethane diisocyanate)
is a respiratory sensitizer. Once sensitized, subsequent low-level exposures may trigger asthmatic reactions. Respiratory protection is essential during spray application and in poorly ventilated spaces. See Section 8.
Section 3. Composition/Information on Ingredients
Substance/Mixture: Mixture
Chemical nature: Single-component moisture-cured polyurethane coating with aromatic isocyanate curative. Balance is proprietary polyurethane resin and pigments (non-hazardous or below regulatory cut-off thresholds).
| Chemical Name | CAS No. | EINECS No. | Concentration (% by mass) | Classification (GHS/CLP) |
|---|---|---|---|---|
| Xylene, mixed isomers | 1330-20-7 | 215-535-7 | 20 - 30% | H226, H312 + H332, H315 |
| Ethylbenzene | 100-41-4 | 202-849-4 | 5 - 10% | H226, H332, H351, H373 |
| 4,4'-Diphenylmethane diisocyanate (MDI) | 101-68-8 | 202-966-0 | < 5.3% | H315, H319, H332, H334, H335, H351, H373 |
Balance: proprietary polyurethane resin, pigments, and additives. Components below disclosure cut-off thresholds or classified non-hazardous under 1910.1200 are not listed.
Section 4. First-Aid Measures
4.1 Description of first-aid measures
Inhalation: Move to fresh air. In case of any discomfort, seek medical attention immediately.
Skin contact: Use hand cleaner, soap, and water. Remove contaminated clothing. If skin irritation continues, consult a doctor.
Eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Ingestion: Do not induce vomiting. Seek immediate medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Inhalation sensitiser with accumulative effects. Risk of dermatitis. May cause lung damage if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
MDI is a respiratory sensitizer; sensitized individuals may react to extremely low subsequent concentrations. Inform treating physician of MDI content. No data available on specific antidotes; treat symptomatically.
Section 5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media: Foam, carbon dioxide, dry powder, fog to cool and control.
Unsuitable extinguishing media: Do NOT use water jets. Containers can become pressurised if contents are contaminated with water.
5.2 Special hazards arising from the substance or mixture
Flammable with toxic fumes.
5.3 Advice for fire-fighters
Wear protective equipment and respirators. Blown or distorted containers should be handled with extreme caution.
Flash point: 27 degrees C (80.6 F), ASTM D56
Section 6. Accidental Release Measures
6.1 Personal precautions, protective equipment, and emergency procedures
Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions
Do not allow to enter drains or sewers, or surface or ground water.
6.3 Methods and materials for containment and cleaning up
Ensure adequate ventilation. Hazardous in liquid state. Solidify by reaction with water before disposal.
Section 7. Handling and Storage
7.1 Precautions for safe handling
Flammable. No open flames. No smoking. Open with care. Cover lid/bung with a cloth while releasing pressure. Generates carbon dioxide gas from reaction with water. Do not seal if contaminated with water due to danger of bursting.
7.2 Conditions for safe storage, including any incompatibilities
Store separately from any reactive substances, especially oxidisers. Keep containers tightly sealed. Adequate ventilation required. Recommended storage temperature: 32-104 F (0-40 C). Shelf life: 12 months unopened when stored per these conditions.
Section 8. Exposure Controls/Personal Protection
8.1 Occupational Exposure Limits
| Component | CAS No. | Jurisdiction | TWA | STEL / Ceiling |
|---|---|---|---|---|
| Xylene, mixed isomers | 1330-20-7 | OSHA PEL | 100 ppm (435 mg/m3) TWA | -- |
| Xylene, mixed isomers | 1330-20-7 | ACGIH TLV | 100 ppm TWA | 150 ppm STEL |
| Xylene, mixed isomers | 1330-20-7 | EU IOELV | 50 ppm (221 mg/m3) TWA | 100 ppm (442 mg/m3) STEL |
| Ethylbenzene | 100-41-4 | OSHA PEL | 100 ppm (435 mg/m3) TWA | -- |
| Ethylbenzene | 100-41-4 | ACGIH TLV | 20 ppm TWA | -- |
| 4,4'-MDI (diphenylmethane diisocyanate) | 101-68-8 | OSHA PEL | none established | -- |
| 4,4'-MDI (diphenylmethane diisocyanate) | 101-68-8 | ACGIH TLV | 0.005 ppm (0.051 mg/m3) TWA | -- |
| 4,4'-MDI (diphenylmethane diisocyanate) | 101-68-8 | NIOSH REL | 0.005 ppm TWA | 0.020 ppm ceiling |
| 4,4'-MDI (diphenylmethane diisocyanate) | 101-68-8 | EU IOELV | 0.005 ppm (0.02 mg/m3) TWA | 0.01 ppm (0.07 mg/m3) STEL |
Note: MDI threshold is extremely low (0.005 ppm TWA); respiratory sensitization is a primary concern. The ACGIH TLV for xylene (100 ppm TWA) aligns with the OSHA PEL; the EU IOELV (50 ppm) is more protective.
8.2 Engineering Controls
Adequate ventilation required. Use local exhaust ventilation during spray application. Where ventilation is insufficient to maintain exposures below OELs, respiratory protection is mandatory. For military/enclosed applications, ensure forced-air ventilation per MIL-PRF-32171B.
8.3 Personal Protective Equipment (PPE)
Respiratory protection: Cartridge-type respirator with organic-fumes cartridge is essential for spraying and for use in areas with inadequate ventilation. For MDI sensitization risk, an air-purifying respirator with an isocyanate-specific cartridge (or supplied-air respirator) is recommended during spray application.
Eye/face protection: Tightly sealed goggles or face shield.
Hand protection: Nitrile rubber gloves.
Skin/body protection: Overalls and safety boots.
Section 9. Physical and Chemical Properties
| Property | Value |
|---|---|
| Physical state | Liquid |
| Color | Various (product available in multiple colors) |
| Odor | Sweetish, mild solvent odor |
| Odor threshold | No data available |
| pH | 8.0 |
| Melting point / freezing point | < -46 degrees C |
| Boiling point / boiling range | 140 degrees C |
| Flash point | 27 degrees C (80.6 F), ASTM D56 |
| Evaporation rate | No data available |
| Flammability (solid, gas) | Not applicable (liquid) |
| Lower/Upper flammability or explosion limits | Refer to xylene component: LEL approx 1.0% vol / UEL approx 7.0% vol |
| Vapor pressure | 14.2 hPa at 20 degrees C |
| Vapor density | No data available |
| Relative density | 1.03 g/cm3 at 20 degrees C (water = 1.00) |
| Solubility | Not miscible with water; reacts with water |
| Partition coefficient (n-octanol/water) | No data available |
| Auto-ignition temperature | > 200 degrees C |
| Decomposition temperature | 200 degrees C |
| Viscosity | Dynamic at 20 degrees C: 80 - 110 KU (Krebs units) (uncured liquid) |
| VOC content | 250 g/L (2.08 lb/gal) (per Navy ASTM F-718) |
| Solids content | 66% by weight / 75.8% by volume (source: current Durabak Company datasheet) |
| Organic solvents | < 24.75% by mass |
| Water content | < 0.1% by mass |
Section 10. Stability and Reactivity
10.1 Reactivity
Reacts with water.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: Could produce static discharge - use earthing. Stable if stored under normal conditions.
10.3 Possibility of hazardous reactions
Stable if stored under normal conditions.
10.4 Conditions to avoid
When exposed to abnormally high temperatures, containers will bulge and possibly burst. Avoid contact with moisture/water in sealed containers (generates CO2; burst risk). Avoid ignition sources; keep away from heat, sparks, and open flames.
10.5 Incompatible materials
Oxidisers. Reacts with water, generating carbon dioxide gas.
10.6 Hazardous decomposition products
Carbon monoxide, carbon dioxide, oxides of nitrogen, and smoke may be produced.
Section 11. Toxicological Information
11.1 Routes of Exposure
Inhalation, skin contact, eye contact, ingestion.
11.2 Acute Toxicity
| Component | Route | Value |
|---|---|---|
| Xylene (CAS 1330-20-7) | Oral LD50 | 4300 mg/kg (rat) |
| Xylene (CAS 1330-20-7) | Dermal LD50 | > 1700 mg/kg (rabbit) |
| Xylene (CAS 1330-20-7) | Inhalation LC50 | 27.6 mg/L / 4 hours (rat) |
| MDI (CAS 101-68-8) | Oral LD50 | 9200 mg/kg (rat) |
| MDI (CAS 101-68-8) | Dermal LD50 | > 5000 mg/kg (rabbit) |
| MDI (CAS 101-68-8) | Inhalation LC50 | 0.49 mg/L / 4 hours (rat) |
11.3 Skin Corrosion/Irritation
Xylene: practically non-irritating with brief contact; prolonged skin contact may defat skin, causing dermatitis.
MDI: slight to moderate irritation; may stain skin.
11.4 Serious Eye Damage/Irritation
Xylene: irritant.
MDI: moderate eye irritation; may cause transient corneal damage.
11.5 Respiratory or Skin Sensitization
Skin and inhalation sensitiser. MDI: respiratory sensitization may occur; chronic inhalation exposure may result in a permanent decrease in lung function; may cause sensitization by skin contact. Prolonged xylene skin contact may cause dermatitis; prolonged xylene inhalation may cause CNS disturbances.
11.6 Germ Cell Mutagenicity
No data available.
11.7 Carcinogenicity
No carcinogenic, mutagenic, or genetic effects have been established for the mixture. Note: MDI (CAS 101-68-8) carries H351 (Suspected of causing cancer) per the individual component hazard classification listed in Section 16.
11.8 Reproductive Toxicity
No data available.
11.9 Specific Target Organ Toxicity - Single Exposure
H335: May cause respiratory irritation.
11.10 Specific Target Organ Toxicity - Repeated Exposure
H373: May cause damage to organs through prolonged or repeated inhalation exposure (MDI component).
11.11 Aspiration Hazard
No data available.
11.12 Additional Notes
Inhalation sensitiser with accumulative effects. Risk of dermatitis. May cause lung damage if swallowed.
Section 12. Ecological Information
12.1 Ecotoxicity
None of the components is persistent in the aquatic environment. Considered harmful to terrestrial vertebrates. May have short-term environmental effects.
12.2 Persistence and degradability
Biodegradable. Once solidified, can be disposed of in landfill sites.
12.3 Bioaccumulative potential
Not bioaccumulative.
12.4 Mobility in soil
Low mobility in soil due to solidification by reaction with water.
12.5 Results of PBT and vPvB assessment
Not applicable.
12.6 Other adverse effects
No data available.
Section 13. Disposal Considerations
13.1 Waste treatment methods
Hazardous in liquid state. Solidify by reaction with water before disposal. Danger of bursting - do not seal. Use reputable waste disposal contractors. Destroy used containers. Consult local official regulations.
European waste catalogue codes (reference): 08 00 00, 08 01 00, 08 01 11 (waste paint and varnish containing organic solvents or other dangerous substances).
Uncleaned packaging: leave container unsealed for 3 to 4 days to solidify from atmospheric moisture, then dispose in landfill.
US disposal: Waste product may be regulated as a hazardous waste under RCRA 40 CFR 261 (flammable, solvent-bearing). If discarded as supplied (unused), this product exhibits the RCRA characteristic of ignitability, waste code D001 (flash point <60 C / 140 F, per 40 CFR 261.21). Unused xylene-bearing waste may also carry listed code U239 (xylene). Confirm the codes for your actual waste stream.
Section 14. Transport Information
14.1 UN number
UN 1263
14.2 UN proper shipping name
PAINT
14.3 Transport hazard class(es)
- ADR: Class 3 (Flammable Liquids), Danger code (Kemler) 30, EA code 127, HAZCHEM code 3(Y)
- IMDG: Class 3 (Flammable Liquids), EMS F-E~S-E
- IATA: Class 3 (Flammable Liquids)
- IMO class: 3
14.4 Packing group
III
14.5 Environmental hazards
Marine pollutant: ND (Not Dangerous)
14.6 Special precautions for user
Keep away from ignition sources during transport. Protect containers from physical damage.
14.7 Additional information
For ADR and IMDG: transport and packing are in accordance with the regulation for limited quantities (ADR LQ: 1 L and 4 L; transport category 3). Product is therefore non-dangerous goods when shipped as limited quantities.
US DOT (49 CFR): UN1263, PAINT, Class 3, Packing Group III. Limited quantity = inner packagings not exceeding 5 L (1.3 gal) per 49 CFR 173.150; consumer-quantity reliefs may apply to retail quart/gallon packaging.
Section 15. Regulatory Information
15.1 US Federal
TSCA (Toxic Substances Control Act, 15 USC 2601): All components are active or exempt on the US TSCA Inventory. TSCA 8(a) PAIR and 8(c) SAR records apply to MDI.
SARA Title III (EPCRA):
- Section 302/304 Extremely Hazardous Substances: No extremely hazardous substances present; reportable quantity not applicable.
- Section 311/312 Hazard categories: Flammable liquid; Acute health hazard (skin/respiratory irritation, sensitization); Chronic health hazard (repeated exposure organ toxicity, suspected carcinogen).
- Section 313 Toxic Release Inventory: Ethylbenzene (CAS 100-41-4) and xylene (mixed isomers, CAS 1330-20-7) are listed toxic chemicals subject to supplier notification under 40 CFR 372.
Clean Air Act Section 112(b) HAPs: Xylene and ethylbenzene are listed hazardous air pollutants.
Clean Water Act: Ethylbenzene is a Section 307 priority pollutant. Xylene and ethylbenzene are Section 311 hazardous substances.
CERCLA/Superfund: Xylene and ethylbenzene are CERCLA hazardous substances; reportable quantities apply per 40 CFR 302.4.
15.2 California
Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986):
WARNING: This product can expose you to ethylbenzene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
15.3 State Right-to-Know
The following components are listed under the right-to-know regulations of Massachusetts, New Jersey, New York, and Pennsylvania: xylene (mixed isomers, CAS 1330-20-7), ethylbenzene (CAS 100-41-4), and MDI / diphenylmethane diisocyanate (CAS 101-68-8).
15.4 International Inventories
All components of this product are listed or exempt on the following inventories: Australia (AICS), Canada (DSL), China (IECSC), Japan (CSCL), Republic of Korea (KECI), New Zealand (NZIoC), Philippines (PICCS), Taiwan (TCSI), EU/Eurasian (Russia) (EAEU), and Vietnam (VCHEMIS). United States: all components are active or exempt on the TSCA Inventory (see US Federal above).
15.5 VOC Compliance
VOC content: 250 g/L (2.08 lb/gal) as applied. Category: Architectural and Industrial Maintenance (AIM) coating, Industrial Maintenance subcategory.
| Regulatory Authority | Limit (AIM/IM) | Compliance |
|---|---|---|
| US EPA / Federal AIM Rule | 450 g/L | Complies |
| CARB / OTC Model Rule (statewide) | 250 g/L | Complies (at limit) |
| SCAQMD Rule 1113 (Greater Los Angeles) | 100 g/L | DOES NOT COMPLY |
Sold in California. CARB SCM-compliant as an Industrial Maintenance coating at <=250 g/L VOC. NOT available in the SCAQMD (greater Los Angeles) district or other air districts that enforce a 100 g/L Industrial Maintenance limit.
Section 16. Other Information
Revision date: 2026-06-18
Version: 1.0
Full Hazard Statement Abbreviation Key (GHS Rev 7)
| Code | Full Statement |
|---|---|
| H226 | Flammable liquid and vapour |
| H312 | Harmful in contact with skin |
| H315 | Causes skin irritation |
| H319 | Causes serious eye irritation |
| H312 + H332 | Harmful in contact with skin or if inhaled |
| H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
| H335 | May cause respiratory irritation |
| H351 | Suspected of causing cancer |
| H373 | May cause damage to organs through prolonged or repeated inhalation exposure |
Key Safety Notices
CONTAINS ISOCYANATE - POTENTIAL SENSITISER - ENSURE PRECAUTIONS ARE TAKEN. PAY SPECIAL ATTENTION TO STORAGE AND HANDLING REQUIREMENTS. IN CASE OF ANY DISCOMFORT FROM CONTACT WITH THE MIXTURE, ALWAYS SEEK MEDICAL ADVICE.
Notes on This Document
This SDS is the sole M26 Military SDS (MDI/aromatic chemistry). The M26 designation reflects the MIL-PRF-32171B revision B application. M26 uses aromatic MDI chemistry; the aliphatic/UV-stable grade is Durabak-18.
Refer to xylene CAS 1330-20-7 for explosion-limit ranges (approx LEL 1.0% / UEL 7.0% by volume).
Disclaimer
Information presented in good faith and believed to be correct at date of preparation. Users are responsible for verifying current status and suitability for their application. The manufacturer expressly disclaims liability for any and all losses, damages, and/or expenses arising out of storage, handling, use, or disposal of the product.